Search results for "Vibrational modes"

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A Universal Length-Dependent Vibrational Mode in Graphene Nanoribbons

2019

Graphene nanoribbons (GNRs) have attracted considerable interest as their atomically tunable structure makes them promising candidates for future electronic devices. However, obtaining detailed information about the length of GNRs has been challenging and typically relies on low-temperature scanning tunneling microscopy. Such methods are ill-suited for practical device application and characterization. In contrast, Raman spectroscopy is a sensitive method for the characterization of GNRs, in particular for investigating their width and structure. Here, we report on a length-dependent, Raman active low-energy vibrational mode that is present in atomically precise, bottom-up synthesized armch…

530 Physicssubstrate transferSTMFOS: Physical sciencesGeneral Physics and Astronomy02 engineering and technology010402 general chemistryDFT01 natural sciencessymbols.namesakegraphene nanoribbons; Raman spectroscopy; length-dependent mode; STM; substrate transfer; vibrational modes; DFT540 ChemistryMesoscale and Nanoscale Physics (cond-mat.mes-hall)General Materials Sciencevibrational modesCondensed Matter - Materials ScienceCondensed Matter - Mesoscale and Nanoscale Physicsbusiness.industryGeneral EngineeringMode (statistics)Materials Science (cond-mat.mtrl-sci)021001 nanoscience & nanotechnology3. Good health0104 chemical sciencesMolecular vibrationRaman spectroscopysymbols570 Life sciences; biologyOptoelectronicslength-dependent mode0210 nano-technologybusinessRaman spectroscopyGraphene nanoribbonsgraphene nanoribbons
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Vibrational modes of the stibine molecule

2005

International audience; In this paper, we use the algebraic approach to describe the vibrational modes of stibine molecule (of C3v molecular symmetry group) up to 21 quanta. As the stibine molecule exhibits stretch-bend resonances, we build an algebraic pyramidal coupling operator between stretching modes and bending modes adapted to this molecule. The standard deviation associated to the fit of the vibrational levels is 1.75 cm-1.

High excited levels[ PHYS.QPHY ] Physics [physics]/Quantum Physics [quant-ph]StibineAlgebraic approachVibrational modes01 natural sciencesMolecular physicsHot bandchemistry.chemical_compound[PHYS.QPHY]Physics [physics]/Quantum Physics [quant-ph]0103 physical sciencesMolecular symmetryMoleculeSbH3 moleculePhysics::Chemical PhysicsPhysical and Theoretical Chemistry010306 general physicsSpectroscopyCouplingPhysicsQuantitative Biology::Biomolecules010304 chemical physicsGroup (mathematics)Operator (physics)Atomic and Molecular Physics and OpticschemistryMolecular vibrationJournal of Molecular Spectroscopy
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